This season, Supernatural [1] is boldly going where the show has never gone before. In the highly anticipated "Scoobynatural," Sam and Dean find themselves in a rather familiar world with a talking dog and a gang of mystery-solving teens. Yep, the show is "cartoonifying" the boys into Scooby-Doo. At PaleyFest's Supernatural panel on March 20 in LA, we snagged a precious few minutes with Jensen Ackles. Though the Winchester darling had plenty to say about the Scooby-Doo crossover, there was something even more exciting to gush about: his wife, Danneel Ackles, who just popped up on the show [2] for the very first time.

While it was a blast seeing Danneel Ackles take on the role of Sister Jo [3], her husband offered some fun, sweet tidbits about the flow of things off screen. "I think I was more nervous than she was, to be honest," Jensen Ackles told me on the PaleyFest red carpet. "I wanted her to have a great experience, because, you know, this is kind of a show that I'm a cocaptain on, and I wanted to make sure that she was still comfortable enough to do what she's really good at. And she was."

We also spoke to Danneel Ackles on the red carpet [4]. While she insisted their relationship was exactly the same on the Supernatural set, Jensen Ackles admitted there was a bit of an adjustment period when she first arrived. "She was basically like, 'You're acting weird. Stop it, you're freaking me out,'" he said with a laugh. "I'm like, 'Sorry, just, know you, making sure you have everything you need!'" Frankly? Goals.