2001: The year Angelina first witnessed humanitarian issues while filming Lara Croft: Tomb Raider in Cambodia. It was also the same year Angelina began her humanitarian work, earning her the title of UNHCR Goodwill Ambassador. Two: Number of countries in which she holds citizenship; she became a Cambodian citizen in 2004. 1 million: The amount Angelina donated, in dollars, to refugee efforts in Afghanistan before becoming a Goodwill Ambassador. Image Source: Getty / ADRIAN DENNIS