Jake Gyllenhaal is making his second appearance on our sexy movie scenes list, and he's extremely deserving of it. Appearing as shepherd Jack Twist alongside Heath Ledger's Ennis Del Mar, the pair develop a complicated relationship during the 1960s — when being a part of the LGBTQ+ community was still tragically frowned upon. Whilst the story has an incredibly sad ending, it has some of the most raw, passionate, and chemistry-filled sexy movie scenes that the silver screen has ever seen.