Popsugar Entertainment Captain Marvel Captain Marvel Cast Everyone You'll See in Captain Marvel and Who They're Playing 27 March 2018 by Quinn Keaney View On One Page Photo 4 of 6 ADVERTISEMENT () Start Slideshow Share This Link Copy ← Use Arrow Keys → 4 Ben Mendelsohn as the Villain His character might not have an official name, but we do know the Rogue One actor will appear as the film's big bad, the leader of the Skrulls. Previous Next Start Slideshow Captain MarvelMovie CastingMoviesBrie Larson