See 43 Famous TV Couples' First Kisses
43 of the Most Memorable First Kisses on TV
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Regardless of where you fall on the Team Angel vs. Team Spike debate, it's hard to argue that Buffy and Spike's first kiss isn't one of the all-time TV greats. Set at the end of "Buffy the Vampire Slayer"'s famed musical episode, the former enemies turned allies finish the episode with an Old Hollywood-style kiss complete with epic music.
Season 6, episode 7