See 43 Famous TV Couples' First Kisses
43 of the Most Memorable First Kisses on TV
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From the beginning of "The Vampire Diaries," there's always a spark of something in the bickering, occasionally antagonistic interactions between human teenager Elena and bad-boy vampire Damon. It isn't until midway through season three, however, in a moment of high emotions for both of them that Damon throws caution to the wind and kisses Elena for real.
Season 3, episode 10