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43 of the Most Memorable First Kisses on TV
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Fresh off of multiple heartbreaks, Callie isn't looking for love when perky peds surgeon Arizona introduces herself in the bathroom at Joe's Bar. After giving Callie a sweet pep talk (and alluding to the fact that the beloved pastime of the entire "Grey's Anatomy" hospital is gossip), Arizona surprises Callie by planting a kiss on her, then walking away.
Season 5, episode 14