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Slide 32 of 43

Hook and Emma First Kiss

On "Once Upon a Time," Emma had plenty of love interests over the first few seasons. The one that stuck, though, was the bickering dynamic she shared with Captain Hook. Their relationship evolved from enemies to allies and even friends, with a simmering undercurrent of attraction the whole time. When Emma kissed Hook to prove a point during a quest in Neverland, that wasn't pixie dust flying around them — just sparks.

Season 3, episode 5

Image Source: Everett Collection