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Miley Cyrus

The pair were a tween power couple from 2006 to 2007. Aside from starring on the Disney Channel together, the Jonas Brothers also opened for Miley during her Best of Both Worlds tour. The two broke up in 2007, which they later wrote about in their duet "Before the Storm." There were rumours that the two rekindled their romance when she was filming The Last Song in 2009, but she eventually fell for her costar Liam Hemsworth. Nick later confessed his feelings about the whole ordeal in the 2012 Jonas Brother song "Wedding Bells."