Where they met: "Mr. & Mrs. Smith"
When it comes to iconic Hollywood couples, Brad Pitt and Angelina Jolie definitely take the cake. The two met on the set of the steamy action film "Mr. & Mrs. Smith" in 2004. Pitt and Jolie sparked romance rumours at the time, but fiercely denied them due to the fact that Pitt was married to Jennifer Aniston, as reported by Glamour. Pitt and Aniston separated in January 2005, and by the summer of 2005, the "Mr. & Mrs. Smith" costars appeared to be a couple while travelling together in Ethiopia, per People.
The two welcomed their first child, Shiloh, in May 2006, and had twins, Knox Léon and Vivienne, in July 2008. The couple also adopted children Maddox (born 2001), Pax (born 2003), and Zahara (born 2005). In April 2012, Pitt and Jolie got engaged, and later tied the knot in an intimate ceremony on Aug. 23, 2014. The marriage lasted about two years, with Jolie ultimately filing for divorce in September 2016. Since separating, Pitt and Jolie have been in a bitter feud over the custody of their children and division of the multi-million dollar assets.